Leonardo Dicaprio and Gisele Bündchen — Plus More Iconic Oscar Couples

Leonardo Dicaprio and Gisele Bündchen

Remember them? The two dated from 2000 to 2005 and made their red carpet debut at the 2005 Oscars.

Zac Efron and Vanessa Hudgens

High School Musical fans everywhere were ecstatic when this Disney couple walked the red carpet together at the 2009 Oscars.

Jennifer Lopez and Ben Affleck

Who could forget "Bennifer"? They were the original super couple, and although they broke up not long after they walked down the red carpet together at the 2003 Oscars, it still made for a memorable moment.

Michelle Williams and Heath Ledger

The couple walked the red carpet together at the 2006 Oscars. They later split in 2007, just one year before Heath's untimely death.

Heath Ledger and Naomi Watts

And speaking of Heath, before Michelle, he and Naomi were the darlings of the Oscars back in 2004. How quickly we forgot!

Reese Witherspoon and Ryan Phillippe

When Reese was nominated for Best Actress for her performance in Walk the Line in 2006, she and then-husband Ryan made a show-stopping appearance together. Sadly, the couple divorced just a year later.

Beyoncé and Jay-Z

Is this what royalty looks like? It certainly looked that way when the power couple made their Oscars debut in 2005.

Brad Pitt and Gwyneth Paltrow

Before Angelina and Jennifer Aniston, the hottest couple was Brad and Gwyneth. Although they didn't stay together long enough to warrant any cutesy nicknames, their appearance at the 1996 Oscars was definitely an iconic one.

Brad Pitt and Angelina Jolie

We're not sure which was more iconic, Brangelina or Angie's right leg. Either way, their appearance at the 2012 Oscars was hard to forget.

Kate Hudson and Chris Robinson

In 2001, Kate made her Oscars red carpet debut alongside then-husband Chris. Although they divorced in 2007, they left behind this iconic moment.

Will Smith and Jada Pinkett Smith

It's hard to believe the couple made their Oscars red carpet debut 20 years ago! The two attended the 1996 show looking very much like the '90s.

Nicole Kidman and Keith Urban

Nicole made her post-Tom Cruise debut with husband Keith at the 2008 Oscars. Tom who?

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